Is Ni Dmg 2 Paramagnetic
Nickel(II) chloride (or just nickel chloride), is the chemical compound NiCl 2. The anhydrous salt is yellow, but the more familiar hydrate NiCl 2 6H 2 O is green. Dmg level 3 magic items list. Nickel(II) chloride, in various forms, is the most important source of nickel for chemical synthesis. The nickel chlorides are deliquescent, absorbing moisture from the air to form a solution.
Is Ni Dmg 2 Paramagnetic 2
Names | |
---|---|
IUPAC name | |
Other names
| |
Identifiers | |
| |
ChEMBL | |
ChemSpider |
|
ECHA InfoCard | 100.002.201 |
EC Number | |
PubChemCID | |
RTECS number |
|
UNII | |
CompTox Dashboard(EPA) | |
| |
| |
Properties | |
C4H8N2O2 | |
Molar mass | 116.120 g·mol−1 |
Appearance | White/Off White Powder |
Density | 1.37 g/cm3 |
Melting point | 240 to 241 °C (464 to 466 °F; 513 to 514 K) |
Boiling point | decomposes |
low | |
Structure | |
0 | |
Hazards | |
Main hazards | Toxic, Skin/Eye Irritant |
Safety data sheet | External MSDS |
GHS pictograms | |
GHS Signal word | Danger |
H228, H301 | |
P210, P240, P241, P264, P270, P280, P301+310, P321, P330, P370+378, P405, P501 | |
NFPA 704 (fire diamond) | |
Related compounds | |
Hydroxylamine salicylaldoxime | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
verify (what is ?) | |
Infobox references |
Dimethylglyoxime is a chemical compound described by the formula CH3C(NOH)C(NOH)CH3. Its abbreviation is dmgH2 for neutral form, and dmgH for anionic form, where H stands for hydrogen. This colourless solid is the dioxime derivative of the diketone butane-2,3-dione (also known as diacetyl). DmgH2 is used in the analysis of palladium or nickel. Its coordination complexes are of theoretical interest as models for enzymes and as catalysts. Many related ligands can be prepared from other diketones, e.g. benzil.
Preparation[edit]
Dimethylglyoxime can be prepared from butanone first by reaction with ethyl nitrite to give biacetyl monoxime. The second oxime is installed using sodium hydroxylamine monosulfonate:[1]
Complexes[edit]
Dimethylglyoxime is used to detect and quantify nickel, which forms the bright red complex nickel bis(dimethylglyoximate) (Ni(dmgH)2). The reaction was discovered by L. A. Chugaev in 1905.[2]
It's a means to buy things. Dmg 5e class wealth level. I tend to completely ignore individual treasures and give out about one hoard per level.That's about 2500gp each.What are they going to spend it on?The basics of adventuring gear is pretty simple, then there is this really wide gulf where the party has mad dolla, but can't afford anything large, like keeps or merchant inns. Really, what do you want from cash? And if you're settling down with keeps and inns, why not take a distraction into a game system that supports intrigue and downtime better?In fact, at the levels of play where you start getting enough cash for some interesting non personal things (say, 5kgp) then having the game turn into somewhere were you use relationships and favours to access the items you want for the purposes you want is actually a lot more fun. Those things are just means to ends.
Cobalt complexes have also received much attention. In chloro(pyridine)cobaloxime[3] the macrocycle [dmgH]22− mimics the macrocyclic ligand found in vitamin B12.
References[edit]
Nickel Dimethylglyoxime
- ^Semon, W. L.; Damerell, V. R. (1930). 'Dimethylglyoxime'. Organic Syntheses. 10: 22. doi:10.15227/orgsyn.010.0022.CS1 maint: multiple names: authors list (link)
- ^Lev Tschugaeff (1905). 'Über ein neues, empfindliches Reagens auf Nickel'. Berichte der Deutschen Chemischen Gesellschaft. 38 (3): 2520–2522. doi:10.1002/cber.19050380317.
- ^Girolami, G. S.; Rauchfuss, T.B.; Angelici, R. J. (1999). Synthesis and Technique in Inorganic Chemistry: A Laboratory Manual (3rd ed.). pp. 213–215.