Ni Dmg 2 2+ Name

Nickel(II) acetate
Names
Systematic IUPAC name
Identifiers
3D model (JSmol)
  • ionic form: Interactive image
  • coordination form (anhydrate): Interactive image
  • coordination form (tetrahydrate): Interactive image
ECHA InfoCard100.006.147
EC Number
PubChemCID
CompTox Dashboard(EPA)
  • InChI=1S/2C2H4O2.Ni/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2
  • ionic form: [Ni+2].[O-]C(=O)C.[O-]C(=O)C
  • coordination form (tetrahydrate): O=C(C)O[Ni-4](OC(C)=O)([O+H2])([O+H2])([O+H2])[O+H2]
Properties
C4H6NiO4
Molar mass176.781 g·mol−1
AppearanceGreen Solid
Odorslight acetic acid
Density1.798 g/cm3 (anhydrous)
1.744 g/cm3 (tetrahydrate)
Melting pointdecomposes when heated [1][2]
Easily soluble in cold water, hot water
SolubilitySoluble in methanol
insoluble in diethyl ether, n-octanol
+4,690.0·10−6 cm3/mol
Structure
monoclinic
P21/c
α = 90°, β = 93.6°, γ = 90°[3]
Lattice volume (V)
471.5
2
distorted octahedral
Hazards
NFPA 704 (fire diamond)
Lethal dose or concentration (LD, LC):
350 mg/kg (rat, oral)
410 mg/kg (mouse, oral)[4]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Nickel(II) acetate is the name for the coordination compounds with the formula Ni(CH3CO2)2·x H2O where x can be 0, 2, and 4. The green tetrahydrate Ni(CH3CO2)2·4 H2O is most common. It is used for electroplating.

Ni(CN) 4 2-= Ni 2+ + 4CN-. In Ni(CN) 4 2-, there is Ni 2+ ion for which the electronic configuration in the valence shell is 3d 8 4s 0. In presence of strong field CN-ions, all the electrons are paired up. The empty 4d, 3s and two 4p orbitals undergo dsp 2 hybridization to.

Synthesis and structure[edit]

The compound can be prepared by treating nickel or nickel(II) carbonate with acetic acid:

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NiCO3 + 2 CH3CO2H + 3 H2O → Ni(CH3CO2)2·4 H2O + CO2

The green tetrahydrate has been shown by X-ray crystallography to adopt an octahedral structure, the central nickel centre being coordinated by four water molecules and two acetate ligands.[5] It may be dehydrated in vacuo, by reaction with acetic anhydride,[6] or by heat.[7]

Safety[edit]

Nickel salts are carcinogenic and irritate the skin.

References[edit]

Ni Dmg 2 2+ NameNi dmg 2 2+ name list

Ni Dmg 2 2+ Name Meaning

  1. ^M. A. Mohamed, S. A. Halawy, M. M. Ebrahim: 'Non-isothermal decomposition of nickel acetate tetrahydrate', in: Journal of Analytical and Applied Pyrolysis, 1993, 27 (2), S. 109–110. doi:10.1016/0165-2370(93)80002-H.
  2. ^G. A. M. Hussein, A. K. H. Nohman, K. M. A. Attyia: 'Characterization of the decomposition course of nickel acetate tetrahydrate in air', in: Journal of Thermal Analysis and Calorimetry, 1994, 42, S. 1155–1165; doi:10.1007/BF02546925.
  3. ^Downie, T. C.; Harrison, W.; Raper, E. S.; Hepworth, M. A. (15 March 1971). 'A three-dimensional study of the crystal structure of nickel acetate tetrahydrate'. Acta Crystallographica Section B. 27 (3): 706–712. doi:10.1107/S0567740871002802.
  4. ^'Nickel metal and other compounds (as Ni)'. Immediately Dangerous to Life and Health Concentrations (IDLH). National Institute for Occupational Safety and Health (NIOSH).
  5. ^Van Niekerk, J. N.; Schoening, F. R. L. (1953). 'The crystal structures of nickel acetate, Ni(CH3COO)2·4H2O, and cobalt acetate, Co(CH3COO)2·4H2O'. Acta Crystallogr.6 (7): 609–612. doi:10.1107/S0365110X5300171X.
  6. ^Lascelles, Keith; Morgan, Lindsay G.; Nicholls, David; Beyersmann, Detmar (2005). 'Nickel Compounds'. Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a17_235.pub2.
  7. ^Tappmeyer, W. P.; Davidson, Arthur W. (1963). 'Cobalt and Nickel Acetates in Anhydrous Acetic Acid'. Inorg. Chem.2 (4): 823–825. doi:10.1021/ic50008a039.
AcOHHe
LiOAcBe(OAc)2
BeAcOH
B(OAc)3AcOAc
ROAc
NH4OAcAcOOHFAcNe
NaOAcMg(OAc)2Al(OAc)3
ALSOL
Al(OAc)2OH
Al2SO4(OAc)4
SiPSClAcAr
KOAcCa(OAc)2Sc(OAc)3Ti(OAc)4VO(OAc)3Cr(OAc)2
Cr(OAc)3
Mn(OAc)2
Mn(OAc)3
Fe(OAc)2
Fe(OAc)3
Co(OAc)2,
Co(OAc)3
Ni(OAc)2Cu(OAc)2Zn(OAc)2Ga(OAc)3GeAs(OAc)3SeBrAcKr
RbOAcSr(OAc)2Y(OAc)3Zr(OAc)4NbMo(OAc)2TcRu(OAc)2
Ru(OAc)3
Ru(OAc)4
Rh2(OAc)4Pd(OAc)2AgOAcCd(OAc)2InSn(OAc)2
Sn(OAc)4
Sb(OAc)3TeIAcXe
CsOAcBa(OAc)2HfTaWReOsIrPt(OAc)2AuHg2(OAc)2,
Hg(OAc)2
TlOAc
Tl(OAc)3
Pb(OAc)2
Pb(OAc)4
Bi(OAc)3PoAtRn
FrRaRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg
La(OAc)3Ce(OAc)xPrNdPmSm(OAc)3Eu(OAc)3Gd(OAc)3TbDy(OAc)3Ho(OAc)3ErTmYb(OAc)3Lu(OAc)3
AcThPaUO2(OAc)2NpPuAmCmBkCfEsFmMdNoLr

Ni Dmg 2 2 Name Ideas

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